Identification and characterisation of high energy density P2-type Na2/3[Ni1/3-:Y/2Mn2/3-y/2Fey]O2compounds for Na-ion batteries

Somerville JW, House RA, Tapia-Ruiz N, Sobkowiak A, Ramos S, Chadwick AV, Roberts MR, Maitra U, Bruce PG

The composition space between MnO2, NaFeO2, and Na[Ni1/2Mn1/2]O2 has been explored with the goal of identifying Earth-abundant single-phase P2 cathode materials. This has led to the identification of two compounds, P2-Na2/3[Ni1/3-y/2Mn2/3-y/2Fey]O2 (y = 1/6, 1/3) which exhibit state of the art specific energies. These materials were further evaluated through galvanostatic cycling and X-ray absorption spectroscopy.